浙江師范大學化學與生命科學學院導師：吳廷華 正文

　　姓名：吳廷華　
　　性別：男　
　　職稱：教授　
　　所在學院：化學與生命科學學院　

　　個人簡介：
　　吳廷華，男，理學博士，浙江師范大學生化學院教授。
　　1994.9-1999.6，師從著名物理化學家萬惠霖院士攻讀博士學位，1999年6月獲廈門大學物理化學專業博士學位，同年被評上副教授。2000年創辦了浙江師范大學物理化學研究所，時任副所長（萬惠霖院士任所長）。2004年晉升教授。2009年獲得包玉剛獎學金去美國賓夕法尼亞州立大學做高級訪問學者。
　　長期從事低碳烷烴的催化轉化、離子液體中精細化學品的合成等方面的研究工作。借助紅外、脈沖質譜-色譜在線分析，準原位XPS、1HNMR等手段對POM反應機理的探討取得了一些成果，提出了POM的熱解-氧化機理模型和離子液體催化下銨/胺鹽一步法合成季銨鹽的催化機理。至2009年12月，申請者已經在國內外著名期刊（Adv. Synth. Catal., Chem. Commun., J. Catal.等）上發表論文80多篇，SCI收錄30多篇，其中影響因子4.0以上的3篇。同時還建立了校企合作的實驗室，已經把一項科研成果產業化，具有一些產業化的經驗。

　　研究領域
　　多相催化與均相催化；
　　綠色催化與精細化學品合成；
　　功能材料的制備。

　　在研（完成）項目（項目負責人）
　　離子液體催化下銨/胺鹽一步季銨化反應的研究（56萬）（國家自然科學基金）；在研
　　生物質單糖直接合成2、5-二甲基呋喃的新催化反應研究（20萬）（浙江省科技廳項目）；在研
　　尿素醇解法制碳酸二甲酯新工藝的研究（28萬）（浙江省科技廳項目）；完成
　　烯烴現場過氧環氧化制環氧烷催化反應的研究（10萬）（浙江省自然科學基金）；完成
　　尿素醇解法制碳酸二甲酯（25萬）（浙江豐登化工）；完成
　　二氧化碳加氫制甲醇催化劑研究（5萬）（橫向課題）；完成
　　強糠聚合成中試(5萬)（橫向課題）；完成

　　參與研究項目
　　涉及表面吸附的電化學振蕩（國家自然科學基金）；第二
　　非貴金屬型低溫CO和CH4氧化催化劑研究（浙江省自然科學基金）；第二
　　電化學振蕩體系現場拉曼光譜研究與理論模型（浙江省自然科學基金）；第二
　　廢水濃縮中試（衢化錦綸廠）。第二
　
　　現（增）開設課程
　　《催化選論》，授課對象:研究生；
　　《催化研究方法》，授課對象:研究生；
　　《物理化學》，授課對象:本科生；
　　《物理化學實驗》，授課對象:本科生。

　　已發表論文
　　[1] Zhang, Qi Neng, Zhang, Jing, Wu, Ting Hua, Zhou, Xiao Ping, The oxidation of olefins by t-butyl hydrogen peroxide to prepare 1,2-diols over metal oxide catalysts, Catalysis Communications, 2009, 10(9): 1279-1283.
　　[2] Wu, Ying, Wu, Binfu, He, Yiming, Wu, Tinghua, Direct Conversion of Ethane to Ethylene Oxide over Ni-Ag-O Catalyst, Chemistry Letters, 2009, 38(3): 284-285.
　　[3] Yang, Feng, Liu, Zhen, Li, Wen Sheng, Wu, Ting Hua, Zhou, Xiao Ping, The oxidative bromination of methane over Rh/SiO2 catalyst, Catalysis Letters, 2008, 124(3-4): 226-232.
　　[4] Chen, Fei, Wu, Ting Hua, Zhou, Xiao Ping, The photodegradation of acetone over VOx/MgF2 catalysts, Catalysis Communications, 2008, 9(8): 1698-1703.
　　[5] Wu, Ying, Wu, Binfu, Wu, Tinghua, Influence of the preparation method on the performance of nanostructured Zr-Ni-O catalysts, Reaction Kinetics and Catalysis Letters, 2008, 95(1): 29-37.
　　[6] Z. Q. Zheng, T. H. Wu*, J. Wang, X. P. Zhou, Ionic Liquid Catalyzed Alkylation of Ammonium Salts, Advanced Synthesis & Catalysis, 2007 , 349: 1095-1101.
　　[7] Z. Q. Zheng, T. H. Wu*, X. P. Zhou, The synthesis of quaternary ammonium salts from ammonium salts and dialkyl carbonate, Chem. Commun., 2006, 1864-1865.
　　[8] T. H. Wu*, Q. G. Yan, F. L. Mao, Z. J. Niu, Q. N. Zhang, Z. L. Li, H. L. Wan, Partial oxidation of methane to syngas over Rh/SiO2 catalyst using on-line MS, Catalysis Today, 2004, 93-95: 121-127.
　　[9] T. H. Wu*, Q. G. Yan, H. L. Wan, Partial Oxidation of Methane to Hydrogen and Carbon Monoxide over a Ni/TiO2 Catalyst, Journal of Molecular Catalysis A: Chemical, 2005, 226(1): 41-48.
　　[10] Q. G. Yan, T. H. Wu, W. Z. Weng, H. Toghiani, R. K. Toghiani, H. L. Wan, C. U. Pittman Jr, Partial Oxidation of Methane to H2 and CO over Rh/SiO2 and Ru/SiO2 Catalysts, Journal of Catalysis, 2004, 226(2): 247-259.
　　[11] Z. Q. Zheng, T. H. Wu*, R. W. Zheng, Y. Wu, X. P. Zhou, Study on the synthesis of quaternary ammonium salts using imidazolium ionic liquid as catalyst, Catalysis Communications, 2007, 8(1): 39-42.
　　[12] Y. Wu, Y. M. He, T. H. Wu*, T. Chen, W. Z. Weng, H. L. Wan, Influence of some parameters on the synthesis of nanosized NiO material by modified sol–gel method, Materials Letters, 2007, 61: 3174-3178.
　　[13] Y. Wu, Y. M. He, T. H. Wu*, W. Z. Weng, H. L. Wan, Effect of synthesis method on the physical and catalytic property of nanosized NiO, Materials Letters, 2007, 61: 2679-2682.
　　[14] T. H. Wu*, D. M. Lin, Y. Wu, X. P. Zhou, Q. G. Yan, W. Z. Weng, H. L. Wan, In-situ FTIR investigation partial oxidation of methane to syngas over Rh/SiO2 catalyst, J. Natur. Gas Chem., 2007, 16: 316-321.
　　[15] T. H. Wu*, M. Q. Zhu, Z. J. Niu, Y. J. Zhong, Y. Guan, Y. Liu, Q. G. Yan, Z. L. Li, H. L. Wan, Studies on the Performance and Structure of Supported Catalysts for the Partial Oxidation of Methane to Syngas, Journal of Natural Gas Chemistry, 2002, 11: 159-164.
　　[16] Z. L. Li, T. H. Wu, Z. J. Niu, In situ Ranman spectropic studies on the current oscillations during gold electrodissolution in HCl solution, Electrochem. Commun., 2004, 5 (6) : 44-48.
　　[17] Z. L. Li, Z. J. Niu, T. H. Wu, In situ monitoring of potential oscillations in the reduction of IO3- by electrochemical quartz crystal microbalance, Electrochem. Commun., 2003, 5 (4): 297-300.
　　[18] Q. G. Yan, Z. S. Cao, T. H. Wu, W. Z. Weng, H. L. Wan, Carbon deposition on Ni/Al2O3 Catalyst during Oxidation Of Methane to syngas, Studies in Surface Science And Catalyst, 2000, 130: 3549-3555.
　　[19] Q. G. Yan, Z. Sh. Cao, T. H. Wu, W. Z. Weng, H. L. Wan, Mechanistic Studies of Methane Partial Oxidation to synthesis gas over supported Rhodium Catalyst Studies in Surface Science And Catalysis, Studies in Surface Science And Catalyst, 2000, 130: 3555-3560.
　　[20] Z. S. Cao, Q. G. Yan, T. H. Wu, W. Z. Weng, H. L. Wan, Novel Method of Preparing Zeolite membrans from colloidal zeolite Nay, Studies in Surface Science And Catalyst, 2000, 130: 2897-2903.
　　[21] W. Z. Weng, M. S. Chen, Q. G. Yan, T. H. Wu, H. L. Wan, In-Situ Time-Resolved FTIR Investigation on the Reaction-Mechanism of Partial Oxidation of Methane to Syngas over a SiO2- Supported Rh and Ru Catalysts, CHINESE SCIENCE BULLETIN, 2000, 45(24): 2236-2240.
　　[22] W. Z. Weng, M. S. Chen, Q. G. Yan, T. H. Wu, H. L. Wan, Mechanistic Study of Partial Oxidation of Methane to Synthesis Gas over Supported Rhodium and Ruthenium Catalysts Using in-Situ Time-Resolved FTIR Spectroscopy, Catalysis Today, 2000, (63): 317-326.
　　[23] Y. Wu, Y. M. He, T. H. Wu*, W. Z. Weng, H. L. Wan, Preparation, Characterization and Low Temperature Catalytic Performance of Nanostructured Ti-Ni-O, Surface Science & Review, in press.
　　[24] Q. G. Yan, T. H. Wu, W. Z. Weng, Z. S. Cao, H. L. Wan, Synergism in platinum enhance nickel Catalyst for Oxidation Of Methane to syngas, Journal of Natural Gas Chemistry, 2000, 19(1): 18-31.
　　[25] Q. G. Yan, T. H. Wu, W. Z. Weng, H. L. Wan, Mechanistic Study of Carbon deposition on Catalysts for Oxidation of Methane to syngas, Journal of Natural Gas Chemistry, 2000, 19(1): 89-102.
　　[26] Q. G. Yan, T. H. Wu, W. Z. Weng, H. L. Wan, Mechanistic Study of Methane Partial Oxidation to synthesis gas over supported Rhodium Catalyst, Journal of Natural Gas Chemistry, 2000, 19(1): 1-7.
　　[27] Z. S. Chao, T. H. Wu, J. L. Ye, G. Z. Chen, H. L. Wan, 1H MAS NMR Characterization of Hydrogen over silica-supported medium catalyst, Science in China (Series B), 2001, l44(1): 115-121.
[28] WU Tinghua, YAN Qiangu, ZHANG Qineng, NIU Zhenjiang, CHAO Zisheng, YE Jianliang, WAN Huilin, 1H MAS NMR Study of Partial Oxidation of Methane to Syngas over Rh/SiO2 Catalyst, Chinese Journal of Catalysis, 2004, 25(11): 909-914.
　　[29] WU Tinghua, YAN Qiangu, ZHANG Qineng, MAO Fulin, ZHENG Zhuoqun, CHEN Fei, WENG Weizheng, WAN Huilin, FT-IR Study of Methane Dissocation on Surface of Rh/SiO2 Catalyst, Chinese Journal of Catalysis, 2004, 25(12): 928-930.
　　[30] WU Tinghua, YAN Qiangu, LI Shaobin, ZHONG Yijun, NIU Zhenjiang, ZHU Mingqiao, LI Zhelin, WAN Huilin, Partial Oxidation of Methane to Syngas over Rh/SiO2 Catalyst, Chinese Journal of Catalysis, 2003, 24(6): 407-413.
　　[31] WU Tinghua, YAN Qiangu, LU Wei, NIU Zhenjiang, MAO Fulin, ZHANG Qineng, ZHU Mingqiao, LI Zhelin, ZHONG Yijun, WAN Huilin, Effect of Surface Oxygen Concentration on Actication of Methane over Supported Metal Catalysts, Chinese Journal of Catalysis, 2003, 24(10): 755-759.
　　[32] WU Tinghua, LI Shaobin, YAN Qiangu, Effect of Interaction between Nickel and Alumina on Coke Deposition on Ni/Al2O3 Catalyst for Partial Oxidation of Methane to Syngas, Chinese Journal of Catalysis, 2001, 22(5): 501-504.
　　[33] WU Tinghua, XIA Wensheng, WANG Haiyou, WANG Zhongquan, ZHANG Hongbin, WAN Huilin, CAI Qirui, Reaction Energetics for Water Gas Shift Reaction over the Clean and the Oxygenmodified Cu(100) surfaces—Studied by the Bond Order Conservation Approach, Chinese Journal of Chemical Physics, 1998, 11(1): 69-73.
　　[34] WU Tinghua, LUO Jizhong, ZHU Yimin, WAN Huilin, AFM Study on Binary Rare Earth Oxyfluoride Sm-La-O-F Catalysts, Chinese Journal of Catalysis, 1998, 19(6): 605-607.
　　[35] WU Tinghua, WANG Haiyou, WENG Weizheng, CHENG Mingsu, WAN Huilin, Methane Partial Oxidation to Syngas-A Study of the Nature of Active Site over Rh Based Catalyst, Chinese Journal of Catalysis, 1998, 19(6): 498-501.
　　[36] LI Liangcao, WU Tinghua, HU Dechong, YANG Yuannan, Studies on Correlation between the Physico-Chemical Properties and Molecular Parameters of Alkanes, Chinese Journal of Organic Chemistry, 2003, 23(10): 1125-1130.
　　[37] NIU Zhengjiang, WU Tinghua, LI Zhelin, In situ XRD Investigation on the Crystallization Behaviors of Electroless High-Phosphorous Ni-P Alloys, Acta Physico-Chimica Sinica, 2003, 19(8): 705-708.
　　[38] MAO Fu-lin, WU Tinghua*, LIU Ya, GUANG Yan, ZHENG Zhuo-qun, ZHANG Qi-neng, CHENG Fei, Study on the Synthesis of Methyl Carbamate through Alcoholysis of Urea, Natural Gas Chemical Industry, 2005, 30(1): 14-16.
　　[39] ZHENG Zhuo-qun, WU Tinghua*, MAO Fu-lin, ZHANG Qi-neng, CHEN Fei, Thermodynamic Analysis of Methyl Carbamate Synthesis from Urea and Methanol, Natural Gas Chemical Industry, 2004, 29(5): 72-73.
　　[40] MAO Fulin, WU Tinghua, DAI Chunhua, ZHENG Zhuoqun, ZHANG Qineng, CHENG Fei, Analysis of the synthesis of methyl carbamate from urea and methanol by reversed phase high performance liquid chromatography, Chinese Journal of Analysis Laboratory, 2005, 24(8): 85-87.
　　[41] MAO Fulin, WU Tinghua, LIU Ya, ZHENG Zhuoqun, ZHANG Qineng, CHENG Fei, On the synthesis of methyl carbamate through alcoholysis of urea, Journal of Zhejiang Normal University (Natural Sciences), 2005, 28(1): 54-56.
　　[42] ZHENG Zhuoqun, WU Tinghua, MAO Fulin, ZHANG Qineng, CHENG Fei, Thermodynamic Analysis of the Synthesis of Dimethyl Carbonate from Methyl Carbamate and Methanol, Chemical Engineering of Oil and Gas, 2005, 34(2): 87-89.
　　[43] NIU Zhengjiang, NI Yahong, LI Zhelin, WU Tinghua, DU Xiaoguang, Influence of zinc ion on electrochemically synthesis of polyaniline, Journal of Zhejiang Normal University (Natural Sciences), 2005, 28(1): 47-50.
　　[44] LIU Ya, WU Tinghua, MAO Fulin, GUAN Yan, ZHU Mingqiao, Preliminary Studies on the Synthesis of Dimethyl Carbonate by Methyl Carbamate Alcoholysis, GUIZHOU CHEMICAL INDUSTRY, 2005, 30(1): 23-26.
　　[45] DU Xiaoguang, NIU Zhengjiang, LI Zhelin, WU Tinghua, Effects of electrodeposition conditions on the texture of methanesulfonate tin deposits, Electroplating & Finishing, 2004, 23(5): 6-9.
　　[46] DU Xiaoguang, NIU Zhengjiang, YING Taokai, WU Tinghua, LI Zhelin, Effect of Octyl Polyethylene Glycol Phenyl Ether on the Textures of Tin Electrodeposited from Methanesulfonic Acid Baths, Plating & Finishing, 2004, 26(2): 1-4.
　　[47] NIU Zhengjiang, YV Ping, WANG Feihua, LI Zhelin, WU Tinghua, Effects of citric acid on electroless Ni-P alloy deposition rate and properties, Electroplating & Finishing, 2003, 22(5): 23-26.
　　[48] NIU Zhengjiang, SHI Zhongxiang, LI Zhelin, WU Tinghua, Effects of Surfactants on the Texture and Morphology of Tin Coating, ELECTROPLATING & POLLUTION CONTROL, 2003, 23(5): 8-10.
　　[49] ZHU Mingqiao, WU Tinghua, XIE Fangyou, New progress in catalysts for preparation of methanol, Modern Chemical Industry, 2003, 23(3): 18-21.
　　[50] NIU Zhengjiang, WU Tinghua, YANG Fangzu, YAO Shibing, ZHOU Saomin, Electrocatalytic Activity of Electrodeposited Amorphous Fe-Mo Alloy for Hydrogen Evolution Reaction in Alkaline Solution, Materials Protection, 2003, 36(8): 9-12.
　　[51] NIU Zhengjiang, SHEN Jijun, LI Zhelin, WU Tinghua, In Situ XRD Investigation on Structure Change of Electroless Ni-P Alloys, Materials Protection, 2003, 36(70): 45-47.
　　[52] LI Saobin, WU Tinghua, Effect of preparation methods on the catalysts for catalytic preformance the Partial Oxidation of Methane (POM) to Syngas, JOURNAL OF NINGDE TEACHERS COLLEGE(NATURAL SCIENCE), 2002, 14(4): 302-305.
　　[53] ZHU Mingqiao, XIE Fangyou, WU Tinghua, Application of Green Chemistry and Technology in Chemical Industry, Chemical Production and Technology, 2002, 9(4): 27-32.
　　[54] LIN Rui, ZHONG Yijun, WU Tinghua, LUO Mengfei, LIU Weiping, Characterization and Preparation of Ce-Sn-O Complex Oxides, Journal of the Chinese Society of Rare Earths, 2002, 20(3): 203-206.
　　[55] NIU Zhengjiang, WU Jie, WU Tinghua, YAO Shibing, ZHOU Saomin, Study of solderable lead free tin-bismuth alloy electrodeposition, Electroplating & Finishing, 2002, 21(3): 1-5.
　　[56] LI Saobin, WU Tinghua, WANG Xiaoxing, DU Jingxing, HE Yimin, MA Li, HU Xiaochun, Synthesis of urea formaldehyde resin—Using NaOH to adjust pH value,Journal of Zhejiang Normal University (Natural Sciences), 2001, 24(3): 260-264.
　　[57] LI Saobin, WU Tinghua, HE Yimin, DU Jingxing, MIAO Jigeng, A New Synthesis of Urea Formaldehyde Resin, Journal of Quanzhou Normal University, 2001, 19(2): 31-34.
　　[58] Li Shaobin, WU Tinghua, Lin Hong, Fang Yanyun, The Study on Preparation of Syngas Catalysts Ni- Cu/r-Al2O3 and Its Capability, Journal of Nanping Teachers College, 2001, 20(2): 61-64.
　　[59] LI Saobin, WU Tinghua, YV Guojun, ZHAO Hong, Investigation of the Partial Oxidation of Methane (POM) to Syngas over Cu Modified Ni-based Catalyst, JOURNAL OF NINGDE TEACHERS COLLEGE (NATURAL SCIENCE), 2001, 13(4): 313-316.
　　[60] CAO Zisheng, LIN Haiqiang, CHEN Guozhou, WU Tinghua, WAN Huilin, MIN Enze, Synthesis of Ultrafine Zeolite NaY(Ⅰ)—Effect of Light Rare Earth Ions Additive, CHEMICAL JOURNAL　OF CHINESE UNIVERSITIES, 2000, 21(9): 1353-1358.
　　[61] WU Tinghua, YAN Qiangu, WAN Huilin, Partial Oxidation of Methane to Syngas over Nickel-based Perovskite-like Mixed Oxide Catalysts, Journal of Zhejiang Normal University (Natural Sciences), 1999, 22(2): 55-59.
　　[62] YAN Qiangu, LI Jitao, WU Tinghua, WENG Weizheng, WAN Huilin, Effects of supports on partial oxidation of methane to syngas, Natural Gas Chemical Industry, 1999, 24(3): 4-8.
　　[63] WU Tinghua, CHEN Zhong, Application High Resolution Solid State NMR in the Studies of Heterogeneous Catalysis, Journal of Zhejiang Normal University (Natural Sciences), 1998, 21(2): 41-47。

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